Aromatic nitro compounds when treated with cyanide ion departs the nitro group resulting carboxylation exclusively at the ortho-position of...
Aromatic nitro compounds when treated with cyanide ion departs the nitro group resulting carboxylation exclusively at the ortho-position of the departing functionality in a reaction called as the von Richter rearrangement.
References
References
- von Richter, V. (1871), Ber. Dtsch. Chem. Ges., 4, 21, 459, 533.
- Rosenblum, M. (1960), J. Am. Soc. Soc., 82, 3796.
- Ibne-Rasa, K. M. and Koubek, E. (1963), J. Org. Chem., 28, 3240.
- Rogers, G. T. and Ulbricht, T. L. V. (1968), Tetrahedron Lett., 23, 1029.
- Ellis, A. C. and Rae, I. D. (1977), J. Chem. Soc., Chem. Commun., 152.
- Tretyakov, E. V., Knight, D. W. and Vasilevsky, S. F. (1999), J. Chem. Soc., Perkin. Trans. 1, 3721.
- Brase, S., Dahmen, S. and Heuts, J. (1999), Tetrahedron Lett., 40, 6201.
- Shine, H. J., Aromatic Rearrangements, Elsevier : NY, 1967, p. 329. [Review]
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